Scientists have developed a new way to calculate the carbon footprint of batteries needed to store wind and solar power for the electrical grid.
A key problem is that the US electrical grid has virtually no storage capacity, so grid operators can’t stockpile surplus clean energy and deliver it at night, or when the wind isn’t blowing.
To provide more flexibility in managing the grid, researchers have begun developing new batteries and other large-scale storage devices. But the fossil fuel required to build these technologies could negate some of the environmental benefits of installing new solar and wind farms, according to Stanford University scientists.
“We calculated how much energy it will cost society to build storage on future power grids that are heavily supplied by renewable resources,” says Charles Barnhart, a fellow at Stanford University’s Global Climate and Energy Project (GCEP) and lead author of the study. “It turns out that that grid storage is energetically expensive, and some technologies, like lead-acid batteries, will require more energy to build and maintain than others.”
Most of the electricity produced in the United States comes from coal and natural gas-fired power plants. Only about 3 percent is generated from wind, solar, hydroelectric, and other renewable sources. The study considers a future US grid where up to 80 percent of the electricity comes from renewables.
“Wind and solar power show great potential as low-carbon sources of electricity, but they depend on the weather,” says co-author Sally Benson, a research professor of energy resource engineering and the director of GCEP.
“As the percentage of electricity from these sources increases, grid operators will need energy storage to help balance supply with demand. To our knowledge, this study is the first to actually quantify the energetic costs of grid-scale storage over time.”
The total storage capacity of the US grid is less than 1 percent, according to Barnhart. What little capacity there is comes from pumped hydroelectric storage, a clean, renewable technology. When demand is low, surplus electricity is used to pump water to a reservoir behind a dam. When demand is high, the water is released through turbines that generate electricity.
For the study, Barnhart and Benson compared the amount of energy required to build a pumped hydro facility with the energetic cost of producing five promising battery technologies: lead-acid, lithium-ion, sodium-sulfur, vanadium-redox, and zinc-bromine.
“Our first step was to calculate the cradle-to-gate embodied energy,” Barnhart says. “That’s the total amount of energy required to build and deliver the technology—from the extraction of raw materials, such as lithium and lead, to the manufacture and installation of the finished device.”
To determine the amount of energy required to build each of the five battery technologies, Barnhart relied on data collected by Argonne National Laboratory and other sources. The data revealed that all five batteries have high embodied-energy costs compared with pumped hydroelectric storage.
“This is somewhat intuitive, because battery technologies are made out of metals, sometimes rare metals, which take a lot of energy to acquire and purify,” Barnhart says. “Whereas a pumped hydro facility is made of air, water, and dirt. It’s basically a hole in the ground with a reinforced concrete dam.”
After determining the embodied energy required to build each storage technology, Barnhart’s next step was to calculate the energetic cost of maintaining the technology over a 30-year timescale. “Ideally, an energy storage technology should last several decades,” he says. “Otherwise, you’ll have to acquire more materials, rebuild the technology and transport it. All of those things cost energy. So the longer it lasts, the less energy it will consume over time as a cost to society.”
To quantify the long-term energetic costs, Barnhart and Benson came up with a new mathematical formula they dubbed ESOI, or energy stored on investment. “ESOI is the amount of energy that can be stored by a technology, divided by the amount of energy required to build that technology,” Barnhart says. “The higher the ESOI value, the better the storage technology is energetically.”
When Barnhart crunched the numbers, the results were clear. “We determined that a pumped hydro facility has an ESOI value of 210,” he says. “That means it can store 210 times more energy over its lifetime than the amount of energy that was required to build it.”
The five battery technologies fared much worse. Lithium-ion batteries were the best performers, with an ESOI value of 10. Lead-acid batteries had an ESOI value of 2, the lowest in the study. “That means a conventional lead-acid battery can only store twice as much energy as was needed to build it,” Barnhart says. “So using the kind of lead-acid batteries available today to provide storage for the worldwide power grid is impractical.”
Improved cycle life
The best way to reduce a battery’s long-term energetic costs, he says, would be to improve its cycle life—that is, increase the number of times the battery can charge and discharge energy over its lifetime. “Pumped hydro storage can achieve more than 25,000 cycles,” Barnhart says. “That means it can deliver clean energy on demand for 30 years or more. It would be fantastic if batteries could achieve the same cycle life.”
None of the conventional battery technologies featured in the study has reached that level. Lithium-ion is the best at 6,000 cycles, while lead-acid technology is at the bottom, achieving a mere 700 cycles.
“The most effective way a storage technology can become less energy-intensive over time is to increase its cycle life,” Benson says. “Most battery research today focuses on improving the storage or power capacity. These qualities are very important for electric vehicles and portable electronics, but not for storing energy on the grid. Based on our ESOI calculations, grid-scale battery research should focus on extending cycle life by a factor of 3 to 10.”
“In general, we found that the material constraints aren’t as limiting as the energetic constraints,” Barnhart says. “It appears that there are plenty of materials in the Earth to build energy storage. There are exceptions, such as cobalt, which is used in some lithium-ion technologies, and vanadium, the key component of vanadium-redox flow batteries.”
Pumped hydro storage faces another set of challenges. “Pumped hydro is energetically quite cheap, but the number of geologic locations conducive to pumped hydro is dwindling, and those that remain have environmental sensitivities,” Barnhart says.
The study also assessed a promising technology called CAES, or compressed air energy storage. CAES works by pumping air at very high pressure into a massive cavern or aquifer, then releasing the compressed air through a turbine to generate electricity on demand. The Stanford team discovered that CAES has the fewest material constraints of all the technologies studied, as well as the highest ESOI value: 240. Two CAES facilities are operating today in Alabama and Germany.
‘Call to arms’
A primary goal of the study was to encourage the development of practical technologies that lower greenhouse emissions and curb global warming, Barnhart says. Coal-and natural gas-fired power plants are responsible for at least a third of those emissions, and replacing them with emissions-free technologies could have a dramatic impact, he adds.
“There are a lot of benefits of electrical energy storage on the power grid,” he says. “It allows consumers to use power when they want to use it. It increases the amount of energy that we can use from wind and solar, which are good low-carbon sources.”
“I would like our study to be a call to arms for increasing the cycle life of electrical energy storage,” Barnhart says. “It’s really a basic conservative principal: The longer something lasts, the less energy you’re going to use. You can buy a really well-made pair of boots that will last five years, or a shoddy pair that will last only one.”
The Global Climate and Energy Project and its sponsors, ExxonMobil, GE, Schlumberger, and DuPont funded the study, which is published in the journal Energy & Environmental Science.